{"id":1299091,"date":"2018-02-23T19:35:48","date_gmt":"2018-02-24T03:35:48","guid":{"rendered":"http:\/\/www.sandiegochinesepress.com\/press\/?p=1299091"},"modified":"2018-02-23T19:38:17","modified_gmt":"2018-02-24T03:38:17","slug":"science-%e4%bd%99%e9%87%91%e6%9d%83%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e6%98%a5%e8%8a%82%e5%8f%91%e6%96%87%ef%bc%9a%e5%a6%82%e4%bd%95%e8%bf%9b%e8%a1%8c%e7%ab%8b%e4%bd%93%e9%80%89%e6%8b%a9%e6%80%a7","status":"publish","type":"post","link":"https:\/\/www.sandiegochinesepress.com\/press\/science-%e4%bd%99%e9%87%91%e6%9d%83%e6%95%99%e6%8e%88%e5%9b%a2%e9%98%9f%e6%98%a5%e8%8a%82%e5%8f%91%e6%96%87%ef%bc%9a%e5%a6%82%e4%bd%95%e8%bf%9b%e8%a1%8c%e7%ab%8b%e4%bd%93%e9%80%89%e6%8b%a9%e6%80%a7\/.html","title":{"rendered":"Science | \u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u6625\u8282\u53d1\u6587\uff1a\u5982\u4f55\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u6d3b\u5316\uff1f"},"content":{"rendered":"

\u836f\u660e\u5eb7\u5fb7\u4f20\u5a92\u62a5\u9053<\/h4>\n

\u6211\u4eec\u77e5\u9053\uff0c\u6709\u673a\u5206\u5b50\u5927\u591a\u7531\u8fde\u63a5\u4e86\u6c22\u539f\u5b50\u7684\u78b3\u539f\u5b50\u7ec4\u6210\u6846\u67b6\u3002\u5982\u679c\u80fd\u5bf9\u78b3\u6c22\u952e\u8fdb\u884c\u9009\u62e9\u6027\u7684\u5b98\u80fd\u56e2\u5316\uff08functionalization\uff09\uff0c\u5c31\u80fd\u8ba9\u4eba\u7c7b\u5145\u5206\u5229\u7528\u201c\u6709\u673a\u5206\u5b50\u201d\u8fd9\u5ea7\u91d1\u77ff\uff0c\u5728\u533b\u836f\u3001\u519c\u4e1a\u3001\u6750\u6599\u7b49\u9886\u57df\u5e26\u6765\u5de8\u5927\u7684\u5e94\u7528\u4ef7\u503c\u3002\u56e0\u6b64\uff0c\u79d1\u5b66\u754c\u4e5f\u79f0\u78b3\u6c22\u952e\u6d3b\u5316\u4e3a\u5316\u5b66\u9886\u57df\u7684\u5723\u676f\u3002<\/strong><\/p>\n

\"\"<\/a><\/p>\n

\u25b2\u672c\u7bc7\u7efc\u8ff0\u7684\u901a\u8baf\u4f5c\u8005\u4f59\u91d1\u6743\u6559\u6388\uff08Credit: John D. & Catherine T. MacArthur Foundation.\uff09<\/strong><\/p>\n

\u63d0\u5230\u78b3\u6c22\u952e\u6d3b\u5316\uff0c\u5c31\u4e0d\u5f97\u4e0d\u63d0\u7f8e\u56fd\u52a0\u5ddeScripps\u7814\u7a76\u6240\u7684\u8457\u540d\u534e\u4eba\u5b66\u8005\u4f59\u91d1\u6743\u6559\u6388\u4e0e\u4ed6\u7684\u56e2\u961f\u3002\u8fd1\u5e74\uff0c\u8fd9\u652f\u56e2\u961f\u5728\u9876\u7ea7\u5b66\u672f\u671f\u520a\u300a\u79d1\u5b66\u300b\u4e0a\u8fde\u7eed\u53d1\u6587\uff0c\u5728\u78b3\u6c22\u952e\u4fee\u9970\u7684\u7acb\u4f53\u63a7\u5236\u4e0a\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u8fdb\u5c55\u3002\u5927\u5e74\u521d\u4e00\uff0c\u5927\u6d0b\u5f7c\u5cb8\u518d\u6b21\u4f20\u6765\u559c\u8baf\u2014\u2014\u4eca\u65e5\uff0c\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u5728\u300a\u79d1\u5b66\u300b\u6742\u5fd7\u4e0a\u518d\u5ea6\u53d1\u6587<\/strong>\uff0c\u5728\u4e00\u7bc7\u6df1\u5ea6\u7efc\u8ff0\u4e2d\uff0c\u7cfb\u7edf\u5730\u4ecb\u7ecd\u4e86\u4e0d\u5bf9\u79f0\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u7acb\u4f53\u5316\u5b66\u6a21\u578b\u7684\u5efa\u7acb\u548c\u8bbe\u8ba1\u53ef\u4ee5\u52a0\u901f\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u624b\u6027\u8fc7\u6e21\u91d1\u5c5e\u50ac\u5316\u5242\u7684\u7406\u8bba\u57fa\u7840\u3002<\/p>\n

\n
\n
\n
\u4f7f\u7528\u53bb\u5bf9\u79f0\u5316\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u6d3b\u5316<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u4f20\u7edf\u624b\u6027\u6709\u673a\u5408\u6210\u4e3b\u8981\u96c6\u4e2d\u4e8e\u5c06\u4e8c\u7ef4\u5e73\u9762\u78b3\u539f\u5b50\u4e2d\u5fc3\u8f6c\u5316\u4e3a\u4e09\u7ef4\u7acb\u4f53\u7ed3\u6784\uff08\u4f8b\u5982\u4e0d\u5bf9\u79f0\u6c22\u5316\uff0c\u4e0d\u5bf9\u79f0\u73af\u6c27\u5316\u7b49\u7b49\uff09\u3002\u57fa\u4e8eC2\u5bf9\u79f0\u6a21\u578b\u7684\u624b\u6027\u50ac\u5316\u5242\u5728\u5de5\u4e1a\u754c\u5df2\u7ecf\u83b7\u5f97\u4e86\u5e7f\u6cdb\u7684\u5e94\u7528\uff0c\u4e5f\u56e0\u6b64\u88ab\u6388\u4e88\u4e862001\u5e74\u7684\u8bfa\u8d1d\u5c14\u5316\u5b66\u5956\u3002\u76f8\u6bd4\u4e4b\u4e0b\uff0c\u57fa\u4e8e\u4ece\u5bf9\u79f0\u7684\u4e09\u7ef4\u56db\u9762\u4f53\u78b3\u4e2d\u5fc3\u5230\u624b\u6027\u7684\u78b3\u4e2d\u5fc3\u7684\u5b98\u80fd\u56e2\u53bb\u5bf9\u79f0\u5316\uff08desymmetrization\uff09\u5374\u7531\u4e8e\u5e95\u7269\u7684\u7279\u6b8a\u6027\uff08\u9700\u8981\u57fa\u4e8e\u5b98\u80fd\u56e2\u7684\u5bf9\u79f0\u9762\u7684\u5b58\u5728\uff09\u500d\u53d7\u5c40\u9650\u3002\u4f46\u662f\uff0c\u5982\u679c\u6211\u4eec\u5c06\u78b3\u6c22\u952e\u89c6\u4e3a\u53ef\u4ee5\u53cd\u5e94\u7684\u5b98\u80fd\u56e2\uff0c\u5927\u591a\u6570\u6709\u673a\u5206\u5b50\u4e2d\u7684\u591a\u4e2a\u78b3\u539f\u5b50\u5f80\u5f80\u5b58\u5728\u57fa\u4e8e\u78b3\u6c22\u952e\u7684\u5bf9\u79f0\u9762\u6216\u955c\u9762\uff0c\u56e0\u6b64\u901a\u8fc7\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u53bb\u5bf9\u79f0\u5316\u5c06\u6709\u5e7f\u9614\u7684\u5e94\u7528\u524d\u666f\u3002<\/strong>\u5148\u524d\uff0c\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u4f7f\u7528MPAA\uff08mono-N-protected amino acid\uff09\u914d\u4f53\uff0c\u7ed3\u5408Pd(II)\/Pd(0)\u50ac\u5316\u5faa\u73af\uff0c\u5bf9\u542b\u6709\u5421\u5576\u5bfc\u5411\u57fa\u7684\u5e95\u7269\u8fdb\u884c\u53bb\u5bf9\u79f0\u5316\uff0c\u8bc1\u660e\u4e86\u5176\u53ef\u884c\u6027\u3002\u800cMPAA\u914d\u4f53\u5bb9\u6613\u83b7\u53d6\u548c\u4fee\u9970\u7684\u7279\u6027\uff0c\u66f4\u8ba9\u4eba\u5bf9\u5176\u5e94\u7528\u524d\u666f\u5927\u4e3a\u770b\u597d\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u25b2\u6709\u673a\u5206\u5b50\u4e2d\u7684\u591a\u4e2a\u78b3\u539f\u5b50\u5f80\u5f80\u5b58\u5728\u57fa\u4e8e\u78b3\u6c22\u952e\u7684\u5bf9\u79f0\u9762\u6216\u955c\u9762\uff08\u56fe\u7247\u6765\u6e90\uff1a\u300a\u79d1\u5b66\u300b\uff09<\/strong><\/p>\n

\"\"<\/a><\/p>\n

\u25b2\u57fa\u4e8ePd(II)\/Pd(0)\u50ac\u5316\uff0c\u6c28\u57fa\u9178\u884d\u751f\u914d\u4f53\u80fd\u5bf9\u73af\u4e01\u57fa\u5316\u5408\u7269\u8fdb\u884c\u53bb\u5bf9\u79f0\u5316\uff08\u56fe\u7247\u6765\u6e90\uff1a\u300a\u79d1\u5b66\u300b\uff09<\/strong><\/p>\n

\u867d\u7136MPAA\u914d\u4f53\u4ecd\u6709\u5f88\u5927\u7684\u5c40\u9650\u6027\uff0c\u4f46\u662f\u5bf9\u5176\u8fdb\u4e00\u6b65\u7684\u673a\u7406\u7814\u7a76\u5e26\u6765\u4e86\u65b0\u7684\u601d\u8def\u3002<\/strong>\u9996\u5148\uff0c\u7ecf\u5178\u7684C2\u5bf9\u79f0\u6a21\u578b\u662f\u8bbe\u8ba1\u624b\u6027\u50ac\u5316\u5242\u7684\u91cd\u8981\u7406\u8bba\u57fa\u7840\uff0c\u4f46\u5728\u78b3\u6c22\u952e\u6d3b\u5316\u53cd\u5e94\u4e2d\uff0cC2\u5bf9\u79f0\u7684\u53cc\u9f7f\u73af\u4e19\u57fa\u6c28\u57fa\u9178\u914d\u4f53\u5374\u5e26\u6765\u5b8c\u5168\u6d88\u65cb\u7684\u4ea7\u7269\uff1b\u5176\u6b21\uff0c\u4f20\u7edf\u7684\u5bfc\u5411\u78b3\u6c22\u952e\u6d3b\u5316\u91cc\uff0c\u6574\u4e2a\u8fc7\u7a0b\u9700\u8981\u5f3a\u914d\u4f4d\u5bfc\u5411\u57fa\u56e2\uff08strongly coordinating directing groups\uff09\u7684\u53c2\u4e0e\u3002\u7136\u800c\u5f53\u5bfc\u5411\u57fa\u56e2\u8fc7\u5f3a\u65f6\uff0c\u4e0d\u4f46\u4f1a\u6291\u5236\u540e\u7eed\u7684\u5b98\u80fd\u5316\u8fc7\u7a0b\uff0c\u5e95\u7269\u4e0e\u8fc7\u6e21\u91d1\u5c5e\u7684\u7ed3\u5408\u80fd\u529b\u8fd8\u4f1a\u8d85\u8fc7\u914d\u4f53\u4e0e\u540e\u8005\u7684\u7ed3\u5408\u80fd\u529b\uff0c\u6216\u4f7f\u914d\u4f53\u5931\u6548\uff0c\u6216\u4ea7\u751f\u6d88\u65cb\u7684\u80cc\u666f\u53cd\u5e94\u800c\u5f97\u4e0d\u5230\u7eaf\u7684\u624b\u6027\u5206\u5b50\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u25b2\u53cc\u9f7fAPAO\u914d\u4f53\u4f7f\u5055\u4e8c\u7532\u57fa\u53d1\u751f\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u6d3b\u5316\uff08\u56fe\u7247\u6765\u6e90\uff1a\u300a\u79d1\u5b66\u300b\uff09<\/strong><\/p>\n

\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u501f\u52a9\u8fd9\u4e9b\u539f\u7406\u63d0\u51fa\u4e86\u65b0\u7684\u50ac\u5316\u5242\u8bbe\u8ba1\u7b56\u7565\uff1a\u975eC2\u5bf9\u79f0\u7684\u53cc\u9f7f\u624b\u6027\u914d\u4f53\u9aa8\u67b6\u548c\u5355\u9f7f\u5f31\u914d\u4f4d\u7684\u5e95\u7269\u3002\u4f9d\u636e\u8fd9\u4e2a\u7406\u8bba\u6846\u67b6\uff0c\u8be5\u56e2\u961f\u5408\u6210\u4e86\u4e00\u79cdAPAO\uff08N-acetyl-protected aminomethyl chiral oxazoline\uff09\u914d\u4f53<\/strong>\uff0c\u80fd\u591f\u5bf9\u5f02\u4e01\u9178\u884d\u751f\u7269\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u82b3\u57fa\u5316\u3002\u8fdb\u4e00\u6b65\u7684\u63a2\u7d22\u5219\u8868\u660e\uff0c\u8fd9\u7c7b\u914d\u4f53\u540c\u6837\u80fd\u5bf9\u5f02\u4e01\u9178\u884d\u751f\u7269\u8fdb\u884c\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u70ef\u57fa\u5316\u548c\u7094\u57fa\u5316\u3002\u503c\u5f97\u6b23\u559c\u7684\u662f\uff0c\u6b64\u7c7b\u78b3\u6c22\u952e\u7684\u9009\u62e9\u6027\u5b98\u80fd\u56e2\u5316\u6709\u7740\u826f\u597d\u7684\u4ea7\u7387\u548c\u5f88\u9ad8\u7684\u7acb\u4f53\u9009\u62e9\u6027\u3002<\/strong>\u8003\u8651\u5230\u5f02\u4e01\u9178\u7684\u7acb\u4f53\u9009\u62e9\u6027\u7f9f\u5316\u5bf9\u4e8e\u5927\u91cf\u5929\u7136\u4ea7\u7269\u548c\u836f\u7269\u5206\u5b50\u7684\u5408\u6210\u90fd\u5f02\u5e38\u91cd\u8981\uff0c\u8fd9\u4e00\u7a81\u7834\u4e0d\u4ec5\u80fd\u5e26\u6765\u6781\u597d\u7684\u5e94\u7528\u524d\u666f\uff0c\u4e5f\u80fd\u4e3a\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u8bbe\u8ba1\u4e0e\u7814\u7a76\u5e26\u6765\u5b9d\u8d35\u7684\u7ecf\u9a8c\u3002<\/p>\n

\n
\n
\n
\u4e9a\u7532\u57fa\u7684\u7acb\u4f53\u9009\u62e9\u6027\u78b3\u6c22\u952e\u6d3b\u5316<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u5728\u78b3\u6c22\u952e\u6d3b\u5316\u4e2d\uff0c\u4e9a\u7532\u57fa\u7684\u7acb\u4f53\u9009\u62e9\u6027\u78b3\u6c22\u952e\u6d3b\u5316\u4e00\u76f4\u88ab\u89c6\u4e3a\u96be\u70b9<\/strong>\u2014\u2014\u4e3a\u4e86\u5728\u975e\u73af\u72b6\u5e95\u7269\u91cc\u5b9e\u73b0\u8fd9\u4e00\u70b9\uff0c\u6211\u4eec\u4f7f\u7528\u7684\u50ac\u5316\u5242\u5fc5\u987b\u80fd\u533a\u5206\u8f83\u5c0f\u7684\u6c22\u539f\u5b50\u4e0e\u76f8\u5bf9\u8f83\u5927\u7684R\u57fa\u56e2\u3002\u800c\u5f53R\u57fa\u56e2\u7684\u5927\u5c0f\u9010\u6e10\u63a5\u8fd1\u6c22\u539f\u5b50\u65f6\uff0c\u5bf9\u4e8e\u50ac\u5316\u5242\u7684\u8981\u6c42\u4e5f\u4f1a\u8d8a\u6765\u8d8a\u9ad8\u3002<\/p>\n

\"\"<\/a><\/p>\n

\u25b2\u4e9a\u7532\u57fa\u7acb\u4f53\u9009\u62e9\u6027\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u4e00\u4e2a\u6210\u529f\u6848\u4f8b\uff08\u56fe\u7247\u6765\u6e90\uff1a\u300a\u79d1\u5b66\u300b\uff09<\/strong><\/p>\n

\u9488\u5bf9\u8fd9\u4e00\u96be\u70b9\uff0c\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u7ecf\u8fc7\u5341\u56db\u5e74\u5982\u4e00\u65e5\u7684\u575a\u5b88\uff0c\u7ec8\u4e8e\u5f00\u8f9f\u4e86\u4e00\u6761\u5168\u65b0\u7684\u9053\u8def\u3002<\/strong>\u5148\u524d\uff0c\u4e0d\u5c11\u5de5\u4f5c\u5229\u7528\u5f3a\u53cc\u9f7f\u5bfc\u5411\u57fa\u56e2\u548c\u5355\u9f7f\u624b\u6027C2\u5bf9\u79f0\u78f7\u9170\u80fa\/\u78f7\u9178\uff0c\u5bf9\u82c4\u57fa\u4e9a\u7532\u57fa\u8fdb\u884c\u78b3\u6c22\u952e\u7684\u6d3b\u5316\u3002\u4f46\u548cMPAA\u914d\u4f53\u5b58\u5728\u7684\u95ee\u9898\u4e00\u6837\uff0c\u8fc7\u5f3a\u7684\u5bfc\u5411\u57fa\u56e2\u4f1a\u5e26\u6765\u201c\u80cc\u666f\u53cd\u5e94\u201d\uff0c\u8fd9\u4e5f\u5f71\u54cd\u5230\u4e86\u6b64\u7c7b\u53cd\u5e94\u7684\u4ea7\u7387\u548c\u7acb\u4f53\u9009\u62e9\u6027\u3002\u4e3a\u6b64\uff0c\u4f59\u91d1\u6743\u6559\u6388\u7684\u56e2\u961f\u4e5f\u5df2\u5f00\u59cb\u4e86\u5168\u65b0\u914d\u4f53\u7684\u8bbe\u8ba1\u3002<\/strong>\u5148\u524d\u7684\u6210\u529f\u7ecf\u9a8c\u8ba9\u4ed6\u4eec\u610f\u8bc6\u5230\uff0c\u55b9\u5b81\u914d\u4f53\u80fd\u8ba9Pd(II)\u50ac\u5316\u7684\u4e9a\u7532\u57fa\u78b3\u6c22\u952e\u82b3\u57fa\u5316\u5728\u5f31\u5bfc\u5411\u57fa\u56e2\u4e0b\u8fdb\u884c\u3002\u7cfb\u7edf\u6027\u7684\u914d\u4f53\u4fee\u9970\u7814\u7a76\u5219\u8868\u660e\uff0c\u516d\u5143\u87af\u5408\u662f\u6210\u529f\u53cd\u5e94\u7684\u5173\u952e\uff0c\u987a\u5f0f\u53d6\u4ee3\u5219\u662f\u9ad8\u6d3b\u6027\u3001\u9ad8\u7acb\u4f53\u9009\u62e9\u6027\u7684\u5fc5\u987b\u3002<\/strong>\u57fa\u4e8e\u8fd9\u4e9b\u53d1\u73b0\u548c\u5bf9\u975eC2\u5bf9\u79f0\u7684\u8981\u6c42\uff0c\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u627e\u5230\u4e86\u4e00\u6b3e\u55b9\u5b81\u548c\u6c28\u57fa\u9178\u76f8\u63a5\u5408\u7684\u914d\u4f53\u2014\u2014\u5b83\u5728C1\u4f4d\u5e26\u6709\u5e9e\u5927\u76843,5-\u4e8c\u53d4\u4e01\u57fa\u82ef\u57fa\uff0c\u5728C2\u4f4d\u5e26\u6709\u4e00\u4e2a\u4e59\u57fa\u3002\u65e0\u8bba\u82c4\u57fa\u8fd8\u662f\u666e\u901a\u70f7\u57fa\u78b3\u6c22\u952e\uff0c\u8fd9\u6b3e\u914d\u4f53\u7684\u72ec\u7279\u8bbe\u8ba1\u5747\u80fd\u4fc3\u8fdb\u4e9a\u7532\u57fa\u7684\u78b3\u6c22\u952e\u6d3b\u5316\u3002<\/strong>\u8fd9\u5728\u914d\u4f53\u5f00\u53d1\u548c\u5e95\u7269\u9009\u62e9\u4e0a\uff0c\u90fd\u7ed9\u6211\u4eec\u5e26\u6765\u4e86\u8bf8\u591a\u65e0\u4ef7\u7684\u6d1e\u89c1\u3002<\/p>\n

\n
\n
\n
\u540e\u8bb0<\/strong><\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u201c2002\u5e74\u5728\u5251\u6865\u5f00\u5c55\u7814\u7a76\u91d1\u5c5e\u4e0d\u5bf9\u79f0\u63d2\u5165\u78b3\u6c22\u952e\u65f6\uff0c\u4e3b\u8981\u662f\u53d7\u597d\u5947\u5fc3\u9a71\u4f7f\uff0c\u5e76\u672a\u610f\u8bc6\u5230\u5728\u836f\u7814\u65b9\u9762\u7684\u5e94\u7528\u524d\u666f\u3002\u6709\u70b9\u5c0f\u65f6\u5019\u5728\u5c71\u6da7\u6293\u5c0f\u9c7c\u7684\u611f\u89c9\uff0c\u5b9e\u9a8c\u624b\u6bb5\u975e\u5e38\u539f\u59cb\u4f46\u5145\u6ee1\u4e50\u8da3\uff0c\u201d\u5173\u4e8e\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u610f\u4e49\uff0c\u4f59\u91d1\u6743\u6559\u6388\u70b9\u8bc4\u9053\uff1a\u201c\u73b0\u5728\u770b\u6765\uff0c\u7531\u4e8e\u78b3\u6c22\u952e\u7684\u5b58\u5728\uff0c\u6709\u673a\u5206\u5b50\u7684\u5927\u591a\u6570\u78b3\u4e2d\u5fc3\u90fd\u5b58\u5728\u5bf9\u79f0\u7684\u9b54\u955c\u8ba9\u5316\u5b66\u5bb6\u4eec\u95ef\u5165\u4e00\u4e2a\u5145\u6ee1\u5bf9\u79f0\u6027\u7684\u5206\u5b50\u4e16\u754c\u3002\u800c\u6253\u7834\u8fd9\u4e2a\u9b54\u955c\u6240\u5f62\u6210\u7684\u624b\u6027\u78b3\u91d1\u5c5e\u952e\u53ef\u4ee5\u5343\u53d8\u4e07\u5316\u8f6c\u5316\u6210\u6240\u9700\u8981\u7684\u5b98\u80fd\u56e2\u3002\u8003\u8651\u5230\u624b\u6027\u662f\u751f\u547d\u79d1\u5b66\u7684\u57fa\u77f3\u4e4b\u4e00\uff0c\u6211\u731c\u60f3\u4e0d\u5bf9\u79f0\u78b3\u6c22\u952e\u6d3b\u5316\u7684\u5e94\u7528\u5c06\u8fdc\u8fdc\u8d85\u51fa\u6709\u673a\u5408\u6210\u7684\u8303\u7574\u3002<\/strong>\u201d<\/p>\n

\u5728\u8fc7\u53bb\u4e00\u4e2a\u4e16\u7eaa\u91cc\uff0c\u4e0d\u5bf9\u79f0\u50ac\u5316\u6781\u5927\u5730\u6539\u53d8\u4e86\u5316\u5b66\u5bb6\u4eec\u5408\u6210\u65b0\u5206\u5b50\u7684\u65b9\u5f0f\uff0c\u4e5f\u5e26\u6765\u4e86\u5927\u91cf\u836f\u54c1\u3001\u519c\u7528\u5316\u5b66\u54c1\u3001\u6740\u866b\u5242\u3001\u65b0\u6750\u6599\u3001\u4ee5\u53ca\u5176\u4ed6\u81ea\u7136\u4ea7\u7269\u3002<\/strong>\u800c\u7406\u89e3\u4e0d\u5bf9\u79f0\u50ac\u5316\u8fc7\u7a0b\u4e2d\u7684\u624b\u6027\u8bf1\u5bfc\uff0c\u4e5f\u662f\u6211\u4eec\u7406\u89e3\u8fd9\u4e9b\u5316\u5b66\u53cd\u5e94\u7684\u91cd\u8981\u5de5\u5177\u3002\u7acb\u4f53\u9009\u62e9\u6027\u7684\u78b3\u6c22\u952e\u6d3b\u5316\u6b63\u6210\u4e3a\u4e0d\u5bf9\u79f0\u50ac\u5316\u7684\u4e00\u7247\u65b0\u5929\u5730\uff0c\u624b\u6027\u78b3\u91d1\u5c5e\u952e\u591a\u53d8\u7684\u53cd\u5e94\u6027\u80fd\u66f4\u662f\u5f97\u5929\u72ec\u539a\uff0c\u5438\u5f15\u4e86\u6765\u81ea\u5de5\u4e1a\u754c\u548c\u5b66\u672f\u754c\u7684\u666e\u904d\u5174\u8da3\u3002\u6beb\u65e0\u7591\u95ee\uff0c\u8fd9\u4e00\u5927\u9886\u57df\u4f1a\u7a81\u7834\u6781\u9650\uff0c\u7ee7\u7eed\u62d3\u5c55\uff0c\u76f4\u5230\u4efb\u4f55\u78b3\u6c22\u952e\u90fd\u80fd\u4ee5\u6781\u9ad8\u7684\u4ea7\u7387\u548c\u7acb\u4f53\u63a7\u5236\uff0c\u81ea\u7531\u8f6c\u5316\u4e3a\u5176\u4ed6\u57fa\u56e2\u3002<\/strong>\u8fd9\u4f1a\u662f\u5316\u5b66\u7684\u4e00\u5927\u91cc\u7a0b\u7891\u3002<\/p>\n

\u6211\u4eec\u518d\u6b21\u795d\u8d3a\u4f59\u91d1\u6743\u6559\u6388\u56e2\u961f\u5728\u78b3\u6c22\u952e\u6d3b\u5316\u9886\u57df\u53d6\u5f97\u7684\u4e00\u7cfb\u5217\u7a81\u7834\u6027\u6210\u679c\uff0c\u4e5f\u671f\u5f85\u672a\u6765\u80fd\u89c1\u8bc1\u66f4\u591a\u60ca\u559c\uff01<\/p>\n

\u81f4\u8c22\uff1a\u7279\u522b\u611f\u8c22\u4f59\u91d1\u6743\u6559\u6388\u4e0e\u672c\u6587\u4f5c\u8005\u4e4b\u4e00\u6731\u5982\u610f\u7684\u62e8\u5197\u6307\u6b63\uff01<\/strong><\/p>\n

\u53c2\u8003\u8d44\u6599\uff1a<\/p>\n

[1]\u00a0St. Denis et al.,\u00a0Enantioselective C(sp3)\u2013H bond activation by chiral transition\u00a0metal catalysts, Science<\/p>\n

\"\"<\/a> \"\"<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"

\u6211\u4eec\u77e5\u9053\uff0c\u6709\u673a\u5206\u5b50\u5927\u591a\u7531\u8fde\u63a5\u4e86\u6c22\u539f\u5b50\u7684\u78b3\u539f\u5b50\u7ec4\u6210\u6846\u67b6\u3002\u5982\u679c\u80fd\u5bf9\u78b3\u6c22\u952e\u8fdb\u884c\u9009\u62e9\u6027\u7684\u5b98\u80fd\u56e2\u5316\uff08functionalization\uff09\uff0c\u5c31\u80fd\u8ba9\u4eba\u7c7b\u5145\u5206\u5229\u7528\u201c\u6709\u673a\u5206\u5b50\u201d\u8fd9\u5ea7\u91d1\u77ff……<\/p>\n","protected":false},"author":3,"featured_media":0,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"footnotes":""},"categories":[16],"tags":[],"class_list":["post-1299091","post","type-post","status-publish","format-standard","hentry","category-science_technology_education"],"_links":{"self":[{"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/posts\/1299091","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/users\/3"}],"replies":[{"embeddable":true,"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/comments?post=1299091"}],"version-history":[{"count":0,"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/posts\/1299091\/revisions"}],"wp:attachment":[{"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/media?parent=1299091"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/categories?post=1299091"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/www.sandiegochinesepress.com\/press\/wp-json\/wp\/v2\/tags?post=1299091"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}